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Question

Chemistry Question on Thermodynamics

Three samples of the same gas A,BA, B and C(γ=3/2)C (\gamma = 3/2) have equal volume initially. Now, the volume of each sample is doubled. For AA , the process is adiabatic; for BB , it is isobaric and for CC , the process is isothermal. If the final pressure are equal for all the three samples, the ratio of their initial pressures is

A

2:1:22 : 1 : \sqrt{2}

B

22:1:22\sqrt{2} : 1 : 2

C

2:1:2\sqrt{2} : 1 : 2

D

2:2:1\sqrt{2} : 2 : 1

Answer

22:1:22\sqrt{2} : 1 : 2

Explanation

Solution

Let PA,PB,PCP_A, P_B, P_C be the initial pressure of the three samples and PP is the final pressure of each. For AA , the process is adiabatic PA(V)3/2=P(2V)3/2,PA=P23/2\therefore P_A (V)^{3/2} = P(2V) ^{3/2} , P_A = P2^{3/2} For BB , the process is isobaric, PB=P\therefore P_B = P For CC , the process is isothermal, PC(V)=P(2V),PC=2P\therefore P_C(V) = P(2V), P_C = 2P Hence PA:PB:PC=23/2:1:2=22:1:2P_A : P_B : P_C = 2^{3/2} : 1 : 2 = 2 \sqrt {2} : 1 : 2