Question
Chemistry Question on Thermodynamics
Three samples of the same gas A,B and C(γ=3/2) have equal volume initially. Now, the volume of each sample is doubled. For A , the process is adiabatic; for B , it is isobaric and for C , the process is isothermal. If the final pressure are equal for all the three samples, the ratio of their initial pressures is
A
2:1:2
B
22:1:2
C
2:1:2
D
2:2:1
Answer
22:1:2
Explanation
Solution
Let PA,PB,PC be the initial pressure of the three samples and P is the final pressure of each. For A , the process is adiabatic ∴PA(V)3/2=P(2V)3/2,PA=P23/2 For B , the process is isobaric, ∴PB=P For C , the process is isothermal, ∴PC(V)=P(2V),PC=2P Hence PA:PB:PC=23/2:1:2=22:1:2