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Question

Chemistry Question on packing efficiency

The yellow colour in NaClNaCl crystals is due to

A

excitation of electrons in F-centres

B

reflection of light from ClCl^- ions on the surface

C

refraction of light from Na+Na^+ ions

D

all of the above

Answer

excitation of electrons in F-centres

Explanation

Solution

The yellow colour is due to metal excess defect of anionic valency. Na+Na ^{+}ion deposited on the surface of crystal of NaClNaCl. The ClCl ^{-}ion diffused to form NaClNaCl. This happens by loss of electron from NaNa to Na+Na ^{+}at FF centres.