Question
Question: The work function of a cathode is estimated using light of wavelength 310±1 nm. The stopping potenti...
The work function of a cathode is estimated using light of wavelength 310±1 nm. The stopping potential is measured to be 500±1mv. hce=1240vnm (known precisely). What is the error e (in %) in work function. Find value of 10e by rounding off to nearest integer.
4
Solution
The energy of the incident photon is given by E=λhc. The work function ϕ and the maximum kinetic energy of the emitted electron Kmax are related by Einstein's photoelectric equation: E=ϕ+Kmax. The maximum kinetic energy is related to the stopping potential Vs by Kmax=eVs.
Thus, the work function is given by ϕ=E−Kmax=λhc−eVs.
We are given ehc=1240 V nm. This implies λhc=λ1240×e. To express energy in eV, we can write eλhc=λ1240, where λ is in nm. This gives the photon energy in eV. The stopping potential Vs in Volts gives the maximum kinetic energy in eV directly (Kmax,eV=Vs).
Given values: Wavelength λ=310 nm, with uncertainty Δλ=1 nm. Stopping potential Vs=500 mV =0.500 V, with uncertainty ΔVs=1 mV =0.001 V.
First, calculate the value of the work function ϕ. Photon energy EeV=310 nm1240 eV nm=4 eV. Maximum kinetic energy Kmax,eV=Vs=0.500 V =0.5 eV. Work function ϕ=EeV−Kmax,eV=4 eV−0.5 eV=3.5 eV.
Next, calculate the error in the work function ϕ. The work function is a function of λ and Vs: ϕ(λ,Vs)=λhc−eVs. The absolute error in ϕ is given by Δϕ=∂λ∂ϕΔλ+∂Vs∂ϕΔVs. ∂λ∂ϕ=−λ2hc ∂Vs∂ϕ=−e So, Δϕ=−λ2hcΔλ+∣−e∣ΔVs=λ2hcΔλ+eΔVs.
To express Δϕ in eV, we divide by e: ΔϕeV=eΔϕ=eλ2hcΔλ+ΔVs. Using ehc=1240 V nm: ΔϕeV=λ2 nm21240 V nmΔλ nm+ΔVs V. ΔϕeV=λ21240Δλ+ΔVs (in Volts, which is equivalent to eV for energy).
Substitute the values: λ=310 nm, Δλ=1 nm. Vs=0.5 V, ΔVs=0.001 V.
ΔϕeV=(310)21240×1+0.001 ΔϕeV=961001240+0.001 ΔϕeV=9610124+10001 ΔϕeV=9610×1000124×1000+9610×1=9610000124000+9610=9610000133610=96100013361 eV.
The percentage error in the work function is e=ϕΔϕ×100%. e=3.5 eV13361/961000 eV×100% e=96100013361×3.51×100 e=961013361×3.51 e=9610×3.513361=3363513361 e≈0.39722%
We are asked to find the value of 10e by rounding off to the nearest integer. 10e≈10×0.39722=3.9722. Rounding off to the nearest integer, we get 4.
The final answer is 4.
Explanation of the solution:
- Calculate the work function ϕ using the formula ϕ=λhc−eVs and the given values, converting to eV.
- Determine the formula for the absolute error in ϕ using error propagation: Δϕ=∂λ∂ϕΔλ+∂Vs∂ϕΔVs.
- Calculate the partial derivatives and substitute them into the error formula.
- Calculate the value of the absolute error Δϕ in eV using the given uncertainties Δλ and ΔVs.
- Calculate the percentage error e=ϕΔϕ×100%.
- Calculate 10e and round it to the nearest integer.
The final answer is 4.