Solveeit Logo

Question

Question: The work-done by a gas molecule in an isolated system is given by, $W = \alpha \beta^2 e^{-\frac{x^2...

The work-done by a gas molecule in an isolated system is given by, W=αβ2ex2αkTW = \alpha \beta^2 e^{-\frac{x^2}{\alpha kT}}, where x is the displacement, k is the Boltzmann constant and T is the temperature, α\alpha and β\beta are constants. Then the dimension of β\beta will be :

[JEE(Main)-2021]

A

[ML^2 T^-2]

B

[MLT^-2]

C

[M^2 LT^2]

D

[M^0 L T^0]

Answer

[MLT^-2]

Explanation

Solution

Given the work done,

W=αβ2ex2αkTW = \alpha \beta^2 e^{-\frac{x^2}{\alpha kT}},

we note that:

  • WW has dimensions of energy, i.e., [W]=ML2T2[W] = ML^2T^{-2}.
  • The exponential term must be dimensionless, so the exponent x2αkT\frac{x^2}{\alpha kT} is dimensionless.

Since xx has dimensions of length [x]=L[x]=L and kTkT has dimensions of energy ML2T2ML^2T^{-2}, we have:

x2αkT\frac{x^2}{\alpha kT} is dimensionless [α]=L2ML2T2=M1T2\Rightarrow [\alpha] = \frac{L^2}{ML^2T^{-2}} = M^{-1}T^2.

Now, from the work expression:

[W]=[α][β]2[W] = [\alpha][\beta]^2,

we substitute the dimensions:

ML2T2=(M1T2)[β]2ML^2T^{-2} = (M^{-1}T^2)[\beta]^2.

Thus,

[β]2=ML2T2M1T2=M2L2T4[\beta]^2 = \frac{ML^2T^{-2}}{M^{-1}T^2} = M^{2}L^2T^{-4}.

Taking the square root, we get:

[β]=MLT2[\beta] = ML T^{-2}.