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Question

Chemistry Question on Bohr’s Model for Hydrogen Atom

The wavelength of the radiation emitted, when in a hydrogen atom electron falls from infinity to stationary state one, would be (Rydberg constant =1.097×107m1=1.097\times {{10}^{7}}\,{{m}^{-1}} )

A

91 nm

B

192 nm

C

406 nm

D

9.1×108nm9.1\times {{10}^{-8}}\,nm

Answer

91 nm

Explanation

Solution

1λ=vˉH=RˉH[1n121n22]\frac{1}{\lambda }={{\bar{v}}_{H}}={{\bar{R}}_{H}}\left[ \frac{1}{n_{1}^{2}}-\frac{1}{n_{2}^{2}} \right]
=1.097×107[11212]=1.097\times {{10}^{7}}\left[ \frac{1}{{{1}^{2}}}-\frac{1}{{{\infty }^{2}}} \right]
\therefore \, λ=11.097×107m\lambda =\frac{1}{1.097\times {{10}^{7}}}m
9.11×108m9.11\times {{10}^{-8}}m
91.1×109m91.1\times {{10}^{-9}}m
=91.1nm=91.1\,nm (1nm=109m)(1\,nm={{10}^{-9}}\,m)