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Question

Chemistry Question on Expressing Concentration of Solutions

The volume of ethyl alcohol (density 1.15g/cc1.15\, g/cc) that has to be added to prepare 100cc100\,cc of 0.5M0.5\, M ethyl alcohol solution in water is

A

1.15 cc

B

2 cc

C

2.15 cc

D

2.30 cc

Answer

2 cc

Explanation

Solution

Molarity = mass ×1000 molecular weight × volume of solution =\frac{\text { mass } \times 1000}{\text { molecular weight } \times \text { volume of solution }}
Molecular weight of ethyl alcohol,
C2H5OH=12×2+5+16+1C _{2} H _{5} OH =12 \times 2+5+16+1
=24+22=46gmol1=24+22=46 \,g \,mol ^{-1}
On substituting the values, we get
0.5M= mass ×100046×1000.5\, M =\frac{\text { mass } \times 1000}{46 \times 100}
Mass =0.5×4610=2.3g=\frac{0.5 \times 46}{10}=2.3\, g
\therefore Volume of ethyl alcohol required,
V= mass of ethyl alcohol  density of ethyl alcohol =2.3g1.15g/cc=2ccV=\frac{\text { mass of ethyl alcohol }}{\text { density of ethyl alcohol }}=\frac{2.3\, g }{1.15\, g / cc }=2\, cc