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Question

Chemistry Question on Organic Chemistry- Some Basic Principles and Techniques

The violet colour in the Lassaigne's test of sulphur is due to

A

FeCl3 FeCl_3

B

Na2[Fe(CN)6Na_2[Fe(CN)_6

C

Na4[Fe(CN)5NOS] Na_4[Fe(CN)_5NOS]

D

Fe4[Fe(CN)6]3Fe_4[Fe(CN)_6]_3

Answer

Na4[Fe(CN)5NOS] Na_4[Fe(CN)_5NOS]

Explanation

Solution

Na2[Fe(CN)5NO]+Na2SNa4[Fe(CN)5NOSNa_2[Fe(CN)_5NO] + Na_2S \rightarrow Na_4[Fe(CN)_5NOS]