Question
Chemistry Question on Quantum Mechanical Model of Atom
The velocities of two particles A and B are 0.05 and 0.02ms−1 respectively. The mass of B is five times the mass of A. The ratio of their de- Broglie's wavelength is
A
2:01
B
#VALUE!
C
1:01
D
4:01
Answer
2:01
Explanation
Solution
Given, velocity of particle A=0.05ms−1
Velocity of particle B=0.02ms−1
Let the mass of particle A=x
∴ The mass of particle B=5x
de-Broglie's equation is
λ=mvh
For particle A
λA=x×0.05h...(i)
For particle B
λ=5x×0.02h...(ii)
Eq (i)/(ii)
λBλA=x×0.055x×0.02
λBλA=12
Or 2:1