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Question

Chemistry Question on Solutions

The vapour pressure of two liquids P'P' and Q'Q' are 8080 and 6060 torr respectively. The total vapour pressure of solution obtained by mixing 33 mole of PP and 22 mol of QQ would be

A

140 torr

B

20 torr

C

68 torr

D

72 torr

Answer

72 torr

Explanation

Solution

Mole fraction of P=33+2=35P=\frac{3}{3+2}=\frac{3}{5} Mole fraction of Q=23+2=25Q=\frac{2}{3+2}=\frac{2}{5} Hence, total vapour pressure == (Mole fraction of P×P \times Vapour pressure of P)+(P)+( mole fraction of Q×Q \times Vapour pressure of Q)Q) =(35×80+25×60)=48+24=\left(\frac{3}{5} \times 80+\frac{2}{5} \times 60\right)=48+24 =72=72 torr