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Question: The vapour pressure of a solution containing 2 moles of a solute in 2 moles of water (vapour pressur...

The vapour pressure of a solution containing 2 moles of a solute in 2 moles of water (vapour pressure of pure water = 24mmHg) is

A

24 mm Hg

B

32 mm Hg

C

48 mm Hg

D

12 mm Hg

Answer

12 mmHg

Explanation

Solution

Solution:

  1. Total moles in solution:

    Moles of solute = 2
    Moles of water = 2
    Total moles = 2 + 2 = 4

  2. Mole fraction of water (solvent):

    Xwater=24=0.5X_{\text{water}} = \frac{2}{4} = 0.5

  3. Vapour pressure of the solution (using Raoult's Law):

    Psolution=Xwater×P0=0.5×24mmHg=12mmHgP_{\text{solution}} = X_{\text{water}} \times P^0 = 0.5 \times 24\, \text{mmHg} = 12\, \text{mmHg}