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Question

Question: The vapour density of completely dissociated \(\mathrm { NH } _ { 4 } \mathrm { Cl }\) would be....

The vapour density of completely dissociated NH4Cl\mathrm { NH } _ { 4 } \mathrm { Cl } would be.

A

Slight less than half that of NH4Cl\mathrm { NH } _ { 4 } \mathrm { Cl }

B

Half that of NH4Cl\mathrm { NH } _ { 4 } \mathrm { Cl }

C

Double that of NH4Cl\mathrm { NH } _ { 4 } \mathrm { Cl }

D

Determined by the amount of solid NH4Cl\mathrm { NH } _ { 4 } \mathrm { Cl } in the experiment

Answer

Half that of NH4Cl\mathrm { NH } _ { 4 } \mathrm { Cl }

Explanation

Solution

 Normal molecular weight  experiment al molecular wt. \frac { \text { Normal molecular weight } } { \text { experiment al molecular wt. } }= 1 + α

NH4Cl\mathrm { NH } _ { 4 } \mathrm { Cl }NH3+HCl\mathrm { NH } _ { 3 } + \mathrm { HCl }

α=1\because \alpha = 1 ∴Experimental Molecular wt =  nor.mol.wt. 2\frac { \text { nor.mol.wt. } } { 2 }