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Question: The value of the gas constant (R) calculated from the perfect gas equation is 8.32 joules/gm mole K,...

The value of the gas constant (R) calculated from the perfect gas equation is 8.32 joules/gm mole K, whereas its value calculated from the knowledge of CPC_{P} and CVC_{V} of the gas is 1.98 cal/gm mole K. From this data, the value of J is

A

(a) 4.166muJ/cal4.16\mspace{6mu} J/cal

B

4.186muJ/cal4.18\mspace{6mu} J/cal

C

4.206muJ/cal4.20\mspace{6mu} J/cal

D

4.226muJ/cal4.22\mspace{6mu} J/cal

Answer

4.206muJ/cal4.20\mspace{6mu} J/cal

Explanation

Solution

We know that

CPCV=RJC_{P} - C_{V} = \frac{R}{J}̃ J=RCPCVJ = \frac{R}{C_{P} - C_{V}}

CPCV=1.986mucalgmmolKC_{P} - C_{V} = 1.98\mspace{6mu}\frac{cal}{gm - mol - K},R=8.32JgmmolKR = 8.32\frac{J}{gm - mol - K}

6muJ=8.321.98=4.206muJ/cal\therefore\mspace{6mu} J = \frac{8.32}{1.98} = 4.20 ⥂ \mspace{6mu} J/cal