Question
Question: The value of Bohr’s radius of hydrogen atom is (in cm): (A) \(0.529 \times {10^{ - 8}}\) (B) \(...
The value of Bohr’s radius of hydrogen atom is (in cm):
(A) 0.529×10−8
(B) 0.529×10−10
(C) 0.529×10−12
(D) 0.529×10−6
Solution
The Bohr radius is based on the Bohr model of the atom.
Complete step by step answer:
Bohr’s radius is named after the Danish scientist Niels Bohr. Bohr found that atoms consist of small, dense nuclei with positive electric charge, around which negatively charged electrons orbit in circular paths.
Now, we will find the value of Bohr’s radius for a hydrogen atom.
According to Bohr’s theory we can write that,
mvr=2πnh
Now, we can write the above given equation as
v=2πmrnh
So, we can write that
v2=4π2m2r2n2h2 ……..(1)
We can say that in the case of atoms, centripetal force is equal to the electrostatic force. So, we can write that in the form of equation as
rmv2=r2KZe2
From this, we can say that
v2=rmKZe2 ………….(2)
Now, we will compare equation (1) and (2). So, we will get
4π2m2r2n2h2=mrKZe2
We can write that
r=4π2KZe2mn2h2
Now, we know that r in the above equation is the Bohr radius which is to be found.
K and Z are equal to 1 in case of hydrogen atom.
e is the charge on an electron and it is 4.8×1010esu.
m is the mass of the electron and it is equal to 9.1×10−28g.
n is equal to 1 as hydrogen’s valence orbital has a primary quantum number of 1.
h is the Planck’s constant and its value is 6.62×10−27erg⋅s
Putting all these available values into the equation of Bohr’s radius, we get
r=(4)(3.14)2(1)(1)(4.8×1010)2(9.1×10−28)(1)2(6.62×10−27)
r=0.529×10−8cm=0.529A∘
So, the correct answer is “Option A”.
Note: The Bohr model of the atom was replaced by the Quantum Mechanics model based upon the Schrodinger equation in the 1920’s. However, the Bohr radius is still a useful constant because it represents the smallest mean radius normally attainable by a neutral atom.