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Question: The valency of gold in \[AuCl\] is A. \[1\] B. \[2\] C. \[3\] D. \[4\]...

The valency of gold in AuClAuCl is
A. 11
B. 22
C. 33
D. 44

Explanation

Solution

The valency is defined as the capacity of an element to form bonds with other elements. The element has to combine with other elements to form bonds.

Complete answer:
According to Aufbau’s rule and Hund’s rule the electrons are arranged in the orbitals in specific order. The electrons that are present in the outermost orbital/shell are labeled as valence electrons.
The outermost electrons are the ones which take in chemical bonding upon excitation. The count of the number of electrons on an atom required during bond formation with other atoms is called the valency of that atom.
Thus a chemical compound is formed by combining two or more atoms and in the process the valency of each atom is satisfied. The valency is obtained by considering the atom to reach the nearest noble gas electronic configuration or by filling up the octet.
For example if an atom like carbon has 44 electrons in its outermost shell, the valency of carbon is 44. But if an atom has more than 44 electrons like oxygen which has 66 electrons, the valency is obtained by subtracting the number of valence electrons from the octet number of electrons. Thus the valency of oxygen is 22.
The given compound is gold chloride. It has a single bond between gold atom and chlorine atom. Thus one electron from each of gold and chlorine is involved in the bond in AuClAuCl. The chlorine atom has 77 electrons in its outermost shell. So the valency of chlorine is 87=18 - 7 = 1 .
Since only one bond is formed between gold and chlorine in AuClAuCl, so the chlorine with valency 11 will combine with one gold atom.
Hence the valency of gold in AuClAuCl is 11 , i.e. option A is the correct answer.

Note:
The valency of an element is not fixed. Elements tend to show variable valency depending on the compound formed or the element it combines with. For example gold shows two valencies 1 and 3 and hence it combines with chlorine to form AuClAuCl and AuCl3AuC{l_3} .