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Question: The unit cell of aluminium is a cube with an length of 405 pm. The density of aluminium is \(2.70gcm...

The unit cell of aluminium is a cube with an length of 405 pm. The density of aluminium is 2.70gcm3.2.70gcm^{- 3}. Whit is the structure of unit cell of aluminium?

A

Body – centred cubic cell

B

Face – centred cubic cell

C

End – centred cubic cell

D

Simple cubic cell

Answer

Face – centred cubic cell

Explanation

Solution

d=Z×MNA×V2.70=Z×276.023×1023×(405×1010)3d = \frac{Z \times M}{N_{A} \times V} \Rightarrow 2.70 = \frac{Z \times 27}{6.023 \times 10^{23} \times (405 \times 10^{- 10})^{3}}Z = 4

Hence, structure of aluminium unit cell is fcc of face – centred.