Solveeit Logo

Question

Chemistry Question on Chemical bonding and molecular structure

The total number of 'sigma' and 'Pi' bonds in 2-oxohex-4-ynoic acid is____.

Answer

To determine the total number of sigma (σ\sigma) and pi (π\pi) bonds in 2-oxohex-4-ynoic acid, analyze the structure:
HO-CH2C(=O)CH2CCCH3\text{HO-CH}_2 - \text{C(=O)} - \text{CH}_2 - \text{C} \equiv \text{C} - \text{CH}_3
Count the sigma bonds (σ\sigma-bonds):
6σ6 \, \sigma-bonds in carbon-hydrogen (C-H) bonds.
5σ5 \, \sigma-bonds in carbon-carbon (C-C) single bonds.
2σ2 \, \sigma-bonds in carbon-oxygen (C=O and C-O) bonds.
1σ1 \, \sigma-bond in the hydroxyl (O-H) group.
Total σ\sigma-bonds: 6+5+2+1=146 + 5 + 2 + 1 = 14
Count the pi bonds (π\pi-bonds):
1π1 \, \pi-bond in the C=O bond.
3π3 \, \pi-bonds in the C \equiv C triple bond (2π2 \, \pi-bonds in the triple bond).
Total π\pi-bonds: 1+3=41 + 3 = 4
Therefore, the total number of bonds (sigma and pi) is:
14+4=1814 + 4 = 18