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Question: The threshold frequency for a certain metal is \(3.3\times {{10}^{14}}cycle/sec\). If the incident l...

The threshold frequency for a certain metal is 3.3×1014cycle/sec3.3\times {{10}^{14}}cycle/sec. If the incident light on the metal has a cut-off frequency of 8.2×1014cycle/sec8.2\times {{10}^{14}}cycle/sec. Calculate the cut-off potential for the photoelectron.
A. 2volt2 volt
B. 0.5volt0.5 volt
C. 1volt1 volt
D. 4volt4 volt

Explanation

Solution

Recall Einstein’s photoelectric equation and how it relates the kinetic energy of the photoelectron, the work function and the energy of a photo. Relate these terms with the Planck’s constant and simplify to find the relation between the threshold frequency, cut-off frequency, and the potential.

Formula used:

Complete step by step answer:
We know that Einstein’s photoelectric formula says that the energy of a photon of light is equal to the sum of the work function and the maximum kinetic energy of the photoelectron. The formula is:
E=ϕ+EkE=\phi +{{E}_{k}}
Where, EE is the energy of the photon, ϕ\phi is the work function, and Ek{{E}_{k}} is the kinetic energy of the photoelectron. Here, we can see that, if the photons from the incident light do not have a frequency that is enough to overcome the energy barrier of the work function, then no electrons will be emitted. Thus, EE corresponds to the energy of the incident light, ϕ\phi corresponds to the threshold energy required to displace electrons, and Ek{{E}_{k}} refers to the kinetic energy of the photoelectrons after they are emitted.
We know that, according to the De Broglie equation; E=hvE = hv.
Where, EE is the energy of the photon, hh s the Planck’s constant, and vv is the frequency of the photons.
The threshold energy which is defined as the work function can also be translated as ϕ=hvo\phi = h{{v}_{o}}.
Where, vo{{v}_{o}} is the threshold frequency.
We know that the kinetic energy of an electron can be defined as the product of the charge on an electron and its cut-off potential. Thus, we can rearrange Einstein’s photoelectric equation as:
hv=hvo+eVhv=h{{v}_{o}}+eV
Where, ee is the charge on an electron and VV is the cut-off potential. Rearranging the equation to find the cut-off potential, we get:
V=1e(hvhvo)V=\frac{1}{e}(hv-h{{v}_{o}})
We already know from the given information that:
Charge on electron = e=1.6×1019Ce =1.6\times {{10}^{-19}}C
Planck’s constant = h=6.6×1034Jh = 6.6\times {{10}^{-34}}J
Frequency of incident light = v=8.2×1014Hzv = 8.2\times {{10}^{14}}Hz
Threshold frequency = vo=3.3×1014{{v}_{o}} = 3.3\times {{10}^{14}}
Thus, putting the values in the equation, we get:
V=6.6×10341.6×1019×(8.23.3)×1014voltV=\frac{6.6\times {{10}^{-34}}}{1.6\times {{10}^{-19}}}\times (8.2-3.3)\times {{10}^{14}}volt
Here, we have taken Planck's constant and the order of magnitude of the frequency (1014{{10}^{14}}) as common. Solving the equation further, we get:

& V = 4.125\times 4.9\times {{10}^{-1}}volt \\\ & V = 20.2125\times {{10}^{-1}}volt \\\ & V = 2.02 volt \\\ \end{aligned}$$ Thus, the cut-off potential comes out to be 2.02volts. Rounding it off to get one of the options given, **the answer to this question is ‘A. $2 volt$’.** **Note:** Remember that the $eV$ given here does not mean electron volts. It indicates the charge present on an electron and the cut-off potential of a photoelectron. Please do not confuse the two concepts as the electron volt is a unit of potential.