Question
Question: The temperature of an ideal gas is increased from 120K to 480K. If at 120K the root-mean- square vel...
The temperature of an ideal gas is increased from 120K to 480K. If at 120K the root-mean- square velocity of the gas molecules is V, at 480K it becomes
(A) 4vrms
(B) 2vrms
(C) 2vrms
(D) 4vrms
Solution
We first use the formula of vrms and put the value of temperatures in it. After that we will have two equations one for 120K temperature and another for 480K.
Then we will take the ratio of both the vrms to get a equation of both the vrms i.e. vrms for 120K and vrms for 480K.
After solving the equation, we get the solution.
Complete step by step solution
We have to find the root mean square velocity of the gas, for this we use the formula vrms=M3RT
Where vrms is the root-mean- square velocity, R=8.3144598 Jmol−1 , T is the temperature, M is the mass of one mole.
Now let the root mean square velocity of the gas molecule at120K= V and
Let the root mean square velocity of the gas molecule at 480K =v2
Then vrms at 120K i.e. V =M3RT1 and vrms at 480K =v2=M3RT1 . Where T1 =120K and T2 =480K . Now the ratio of the root mean square velocity at 120K to the ratio of the root mean square velocity at 480K = v2v .
After substituting we get v2v i.e.
v2v=T2T1 now we put the value of T1 =120K and T2 =480K in the equation.
v2v=480120=41 . After solving we get v2v=21
So 2v=v2 , therefore the root mean square speed of gas molecules 480K, will be 2v.
So, the correct option is B.
Note: Remember the formula of vrms and also that vrms∝T i.e. vrms is dependent on temperature. If the temperature increase vrms and vice-versa
Note that RMS velocity is used to predict how fast molecules are moving at a given temperature.
Also remember that the vrms of a gas module is generated from the thermal energy equation i.e. KE=23RT .