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Question

Chemistry Question on anomalous behaviour of beryllium

The structures of beryllium chloride in the solid state and vapour, phase, respectively,are :

A

chain and dimeric

B

chain and chain

C

dimeric and dimeric

D

dimeric and chain

Answer

chain and dimeric

Explanation

Solution

BeCl2 {BeCl_2} exist as (BeCl2)n {(BeCl2)_{n}} polymeric chain in solid form, while BeCl2 {BeCl2} exist as dimer (BeCl2)2 {(BeCl2)2} in vapour phase.