Question
Chemistry Question on Thermodynamics
The standard enthalpy of formation of C2H4(g),CO2(g) and H2O(l) are 52,−394 and −286kJmol−1 respectively. Then the amount of heat evolved by burning 7g of C2H4(g) is
A
1412kJ
B
9884kJ
C
353kJ
D
76kJ
Answer
353kJ
Explanation
Solution
Enthalpy of combustion, is the heat energy that is absorbed or released when one mole of a substance undergoes complete combustion in the presence of excess oxygen under the standard conditions.
Given 2C+2H→C2H4 (g) △H1 = 52KJ mol-1
C+O2→ CO2 (g) △H2 = -394 KJ mol-1
H2 + 21O2 → H2O (g) △H3 = -286 KJ mol-1
For Combustion of C2H4
C2H4 + 3O2 → 2CO2 +2H2O
For △ H → 2 [△H2+△H1] - [△H1]
= 2 [-394+(-286)]- 52
= -1360 - 52
= -1412 KJ mol-1