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Question

Chemistry Question on Thermodynamics

The standard enthalpy of formation of C2H4(g),CO2(g)C_2H_{4(g)}, CO_{2(g)} and H2O(l)H_2O_{(l)} are 52,39452, -394 and 286kJmol1-286\, kJ\, mol^{-1} respectively. Then the amount of heat evolved by burning 7g7\, g of C2H4(g)C_2H_{4(g)} is

A

1412kJ1412\, kJ

B

9884kJ9884\, kJ

C

353kJ353\, kJ

D

76kJ76\, kJ

Answer

353kJ353\, kJ

Explanation

Solution

Enthalpy of combustion, is the heat energy that is absorbed or released when one mole of a substance undergoes complete combustion in the presence of excess oxygen under the standard conditions.

Given 2C+2H→C2H4 (g) △H1 = 52KJ mol-1

C+O2→ CO2 (g) △H2 = -394 KJ mol-1

H2 + 12\frac{1}{2}O2 → H2O (g) △H3 = -286 KJ mol-1

For Combustion of C2H4

C2H4 + 3O2 → 2CO2 +2H2O

For △ H → 2 [△H2+△H1] - [△H1]

= 2 [-394+(-286)]- 52

= -1360 - 52

= -1412 KJ mol-1