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Question

Chemistry Question on coordination compounds

The spin only magnetic moment value (in B.M. unit) of Cr(CO)6Cr(CO)_{6} is

A

00

B

2.842.84

C

4.904.90

D

5.925.92

Answer

00

Explanation

Solution

In Cr(CO)BCr(CO)_{B}, CrCr is present as Cr0Cr^{0} CrCr or Cr0=[Ar]3d54S1Cr^{0}=[Ar] 3d^{5} \, 4S^{-1} COCO being strong field ligand pair up the unpaired electrons of CrCr In this condition, number of unpaired electrons, n=0n=0 Magnetic moment, μ=n(n+2)\mu= \sqrt{n\left(n+2\right)} =0(0+2)=\sqrt{0\left(0+2\right)} =0BM=0 BM