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Question

Chemistry Question on d -and f -Block Elements

The 'Spin only' Magnetic moment for [Ni(NH3)6]2+[Ni(NH_3​)_6​]^{2+} is _____ × 10110^{−1} BM. (given = Atomic number of Ni : 28)

Answer

NH3_3 acts as a weak field ligand with Ni2+^{2+}.
Ni2+=3d8\text{Ni}^{2+} = 3d^8

11111

No. of unpaired electrons=2\text{No. of unpaired electrons} = 2
μ=n(n+2)=8=2.82BM\mu = \sqrt{n(n+2)} = \sqrt{8} = 2.82 \, \text{BM}
28.2×101BM28.2 \times 10^{-1} \, \text{BM}
x=28x = 28

Explanation

Solution

NH3_3 acts as a weak field ligand with Ni2+^{2+}.
Ni2+=3d8\text{Ni}^{2+} = 3d^8

11111

No. of unpaired electrons=2\text{No. of unpaired electrons} = 2
μ=n(n+2)=8=2.82BM\mu = \sqrt{n(n+2)} = \sqrt{8} = 2.82 \, \text{BM}
28.2×101BM28.2 \times 10^{-1} \, \text{BM}
x=28x = 28