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Question

Chemistry Question on GROUP 1 ELEMENTS

The solubilities of carbonates decrease down the magnesium group due to a decrease in :

A

lattice energies of solids

B

hydration energies of cations

C

inter-ionic attraction

D

entropy of solution formation

Answer

hydration energies of cations

Explanation

Solution

Solubilities of carbonates decreases down the group because lattice energy decrease is almost constant while decrease in hydration energy happens sharply. Finally difference of hydration energy and lattice energy decreases thus solubility decreases.