Question
Chemistry Question on Chemical bonding and molecular structure
The shape of XeO2F2 molecule is
A
trigonal bipyramidal
B
square planar
C
tetrahedral
D
see-saw
Answer
see-saw
Explanation
Solution
In XeO2F2, the bonding arrangement around the central
atom Xe is
4s bonds + 1.01/7=5
Hybridisation of Xe = sp3d
sp3d-hybridisation corresponds to trigonal bipyramidal
geometry.
Also, in trigonal bipyramidal geometry, lone pairs remain
present on equatorial positions in order to give less
electronic repulsion.
NOTE According to Bent's rule, the more electronegative atoms must
be present on axial position. Hence, F are kept on axial
positions.