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Question

Chemistry Question on Chemical bonding and molecular structure

The shape of XeO2F2XeO_2F_2 molecule is

A

trigonal bipyramidal

B

square planar

C

tetrahedral

D

see-saw

Answer

see-saw

Explanation

Solution

In XeO2F2XeO_2F_2, the bonding arrangement around the central
atom Xe is
4s4s bonds + 1.01/7=5
Hybridisation of Xe = sp3dsp^3d
sp3sp^3d-hybridisation corresponds to trigonal bipyramidal
geometry.
Also, in trigonal bipyramidal geometry, lone pairs remain
present on equatorial positions in order to give less
electronic repulsion.
NOTE According to Bent's rule, the more electronegative atoms must
be present on axial position. Hence, F are kept on axial
positions.