Question
Question: The shape of \(\text{CH}_{\text{3}}^{\text{+}}\) is ……………….. (planar/bent)....
The shape of CH3+ is ……………….. (planar/bent).
Solution
In sp2 molecule one pi-bond is required to link the double bond between the carbons. Also, only three sigma bonds are formed per carbon atom. The positive charge makes 3 available electrons. It forms 3 single bonds with hydrogen atoms.
Complete step by step answer:
In VSEPR theory, hybridization is the process of adding atomic orbital’s with the new hybrid orbitals, which is appropriate for the pairing of electrons to form chemical bonds. This theory is used to explain molecular geometry and atomic bonding properties.
In sp2 molecule, carbon is sp2hybridized. Here, one pi-bond (π−bond) is required to link the double bond between the carbons. Also, only three sigma bonds (σ−bond)are formed per carbon atom. So, simply it involves the promotion of one electron in the s- orbital to one 2p orbital and thereby, the one s and two p orbitals of the same shell and of equal energies get mixed to form 3 equivalent orbital’s. So, in sp2 hybridization, the 2s orbital is mixed with the two available 2p orbitals (known as 2px and 2py orbitals) out of three 2p orbitals. So, the last or 2pzorbital remains unhybridized. So, we get the formation of the total of the three sp2 orbital’s having one unhybridized p orbital.
Now, CH3+ has sp2 carbon atom. So, that means in its carbonation, carbon is sp2 hybridized. There are 4 valence electrons in the CH3+molecule. The positive charge makes 3 available electrons. It forms 3 single bonds with hydrogen (H) atoms and thereby, forms the planar structure with sp2 hybridization. So, the shape of CH3+ is planer.
Additional information:
Redistribution of the energy of orbitals of individual atoms to give orbital’s of equivalent energy happening when two atomic orbitals combine to form hybrid orbital in a molecule. This process is called hybridization and new orbital’s is hybrid orbitals.
It is not necessary that all the half-filled orbitals must participate in hybridization, even the completely filled.
Hybridization happens only during the bond formation and not in an isolated gaseous atom.
Note: Things should be noted that this mixture of s and p orbital forms the trifocal symmetry and maintains 120∘ between each bond. Also, it should be remembered that all the three orbitals are placed in one plane having 120∘ between each bond. So, also, we can say that the shape of CH3+ is triangular planar.