Solveeit Logo

Question

Question: The shape of \(\text{CH}_{\text{3}}^{\text{+}}\) is ……………….. (planar/bent)....

The shape of CH3+\text{CH}_{\text{3}}^{\text{+}} is ……………….. (planar/bent).

Explanation

Solution

In sp2s{{p}^{2}} molecule one pi-bond is required to link the double bond between the carbons. Also, only three sigma bonds are formed per carbon atom. The positive charge makes 33 available electrons. It forms 33 single bonds with hydrogen atoms.

Complete step by step answer:
In VSEPR theory, hybridization is the process of adding atomic orbital’s with the new hybrid orbitals, which is appropriate for the pairing of electrons to form chemical bonds. This theory is used to explain molecular geometry and atomic bonding properties.
In sp2s{{p}^{2}} molecule, carbon is sp2s{{p}^{2}}hybridized. Here, one pi-bond (πbond)(\pi -\text{bond}) is required to link the double bond between the carbons. Also, only three sigma bonds (σbond)(\sigma -\text{bond})are formed per carbon atom. So, simply it involves the promotion of one electron in the ss- orbital to one 2p2p orbital and thereby, the one ss and two pp orbitals of the same shell and of equal energies get mixed to form 33 equivalent orbital’s. So, in sp2s{{p}^{2}} hybridization, the 2s2s orbital is mixed with the two available 2p2p orbitals (known as 2px2px and 2py2py orbitals) out of three 2p2p orbitals. So, the last or 2pz2pzorbital remains unhybridized. So, we get the formation of the total of the three sp2s{{p}^{2}} orbital’s having one unhybridized pp orbital.
Now, CH3+\text{CH}_{3}^{+} has sp2s{{p}^{2}} carbon atom. So, that means in its carbonation, carbon is sp2s{{p}^{2}} hybridized. There are 44 valence electrons in the CH3+\text{CH}_{3}^{+}molecule. The positive charge makes 33 available electrons. It forms 33 single bonds with hydrogen (H)(\text{H}) atoms and thereby, forms the planar structure with sp2s{{p}^{2}} hybridization. So, the shape of CH3+\text{CH}_{3}^{+} is planer.

Additional information:
Redistribution of the energy of orbitals of individual atoms to give orbital’s of equivalent energy happening when two atomic orbitals combine to form hybrid orbital in a molecule. This process is called hybridization and new orbital’s is hybrid orbitals.
It is not necessary that all the half-filled orbitals must participate in hybridization, even the completely filled.
Hybridization happens only during the bond formation and not in an isolated gaseous atom.

Note: Things should be noted that this mixture of ss and pp orbital forms the trifocal symmetry and maintains 120120{}^\circ between each bond. Also, it should be remembered that all the three orbitals are placed in one plane having 120120{}^\circ between each bond. So, also, we can say that the shape of CH3+\text{CH}_{3}^{+} is triangular planar.