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Question

Chemistry Question on The solid state

The second order Bragg diffraction of X-rays with λ=1.0A˚\lambda = 1.0 \mathring{A} from a set of parallel planes in a metal occurs at an angle 6060^\circ. The distance between the scattering planes in the crystals is

A

0.575A˚0.575 \mathring{A}

B

1.00A˚1.00 \mathring{A}

C

2.00A˚2.00 \mathring{A}

D

1.17A˚1.17 \mathring{A}

Answer

1.17A˚1.17 \mathring{A}

Explanation

Solution

According to Bragg- equation, nλ\, \, \, \, \, \, \, \, \, \, \, \, n\lambda=2d sin θ\theta \, \, \, \, \, \, \, \, \, \, \, \, n=2 lambda=1\, \, \, \, \, \, \, \, \, \, \, \, \, lambda=1 deflected angleθ=60\theta=60^\circ d=?\, \, \, \, \, \, \, \, \, \, \, \, \, d=? Distance between two plane of crystal 2×1=2×d×sin60\, \, \, \, \, \, \, \, \, \, \, \, \, 2 \times 1 = 2 \times d \times sin 60^\circ 2×1=2×d×32\, \, \, \, \, \, \, \, \, \, \, \, \, 2 \times 1 = 2 \times d \times \frac{\sqrt{3}}{2} d=23=21.7=1.17A˚\, \, \, \, \, \, \, \, \, \, \, \, \, \, \, \, \, \, \, \, \, \, \, \, \, \, d=\frac{2}{\sqrt{3}}=\frac{2}{1.7}=1.17\mathring{A}