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Question

Physical Chemistry Question on Thermodynamics

The second law of thermodynamics states that 'whenever a spontaneous process takes place, it is accompanied by an increase in the total energy of the universe.' The equation that satisfies the above law is:

A

ΔSuniverse=SsystemΔSsurroundings\Delta S_{\text{universe}} = S_{\text{system}} - \Delta S_{\text{surroundings}}

B

ΔSuniverse=SsurroundingsΔSsystem\Delta S_{\text{universe}} = S_{\text{surroundings}} - \Delta S_{\text{system}}

C

Ssystem=ΔSuniverse+ΔSsurroundingsS_{\text{system}} = \Delta S_{\text{universe}} + \Delta S_{\text{surroundings}}

D

ΔSuniverse=Ssystem+ΔSsurroundings\Delta S_{\text{universe}} = S_{\text{system}} + \Delta S_{\text{surroundings}}

Answer

ΔSuniverse=Ssystem+ΔSsurroundings\Delta S_{\text{universe}} = S_{\text{system}} + \Delta S_{\text{surroundings}}

Explanation

Solution

The correct option is (D): ΔSuniverse=Ssystem+ΔSsurroundings\Delta S_{\text{universe}} = S_{\text{system}} + \Delta S_{\text{surroundings}}