Question
Question: The Rydberg Constant R for hydrogen is: A) \( R = - \left( {\dfrac{1}{{4\pi {\varepsilon _0}}}} \r...
The Rydberg Constant R for hydrogen is:
A) R=−(4πε01)ch22π2me2
B) R=(4πε01)ch22π2me4
C) R=(4πε01)2c2h22π2me4
D) R=(4πε01)2ch32π2me4
Solution
The Rydberg constant is denoted by the symbol R∞ for heavy metals and RH for hydrogen atoms. It is named after the Swedish physicist Johannes Rydberg, and is a physical constant relating to the electromagnetic spectrum of an atom.
Complete Step By Step Answer:
The value of the Rydberg constant was first found as an empirical fitting parameter but later it was found that its value could be more accurately measured using the Bohr Model. By 2018 the value of R∞ was most accurately found. This constant is used to depict the highest wavenumber of a photon that can be emitted from an atom. The hydrogen spectral series can be expressed in terms of RH and the Rydberg formula.
The value of R∞ can be given by the formula: R∞=8ε02h3cmee4
Where me is the mass of the electron, e is the elementary charge, h is the planck's constant, c is the speed of light.
The value of RH can be calculated by the reduced mass of the electron and can be given by the formula: RH=R∞me+mpmp≈1.09678×107m−1
Where, me is the mass of electrons and mp is the mass of protons.
Therefore we know that, R∞=8ε02h3cmee4 . On simplifying the value of R∞ we get, R=ch32π2me4k2 . Simplifying the value of k as 1/4πε0 we get the value of R as R=(4πε01)2ch32π2me4
The correct answer is Option (D).
Additional Information: The Rydberg formula is used to find out the wavelength emitted when an electron moves between energy levels of an atom. The Rydberg formula applicable to different elements can be given as:
\mathop \nu \limits^\\_ = \dfrac{1}{\lambda } = R\left( {\dfrac{1}{{n_1^2}} - \dfrac{1}{{n_2^2}}} \right)
Where R is the Rydberg Constant.
Note:
In atomic physics, Rydberg Unit of energy, denoted by the symbol Ry corresponds to the energy of the photon, whose wave number is equal to the Rydberg Constant or the ionization energy of a Hydrogen atom in a simplified Bohr Model.