Question
Chemistry Question on States of matter
The root mean square(rms) speed of X2 gas is x m/s at a given temperature. When the temperature is doubled, the X2 molecules dissociated completely into atoms. The root mean square speed of the sample of gas then becomes (in m/s)
2x
x
2x
4x
2x
Solution
The root mean square (rms) speed of gas molecules is directly proportional to the square root of the temperature. Mathematically, it can be expressed as:
v rms=√(3 kT/m)
Where:
- v rms is the rms speed of the gas molecules.
- k is the Boltzmann constant.
- T is the temperature in Kelvin.
- m is the mass of a gas molecule.
Given that the rms speed of X2 gas is m/s x m/s at a given temperature, let's consider the situation when the temperature is doubled. If the X2 molecules dissociate completely into atoms, the mass m in the formula will change, as X2 molecules become two X atoms.
Now, let's analyze the relationship: v rms1 v rms2=T 1 T 2
Since T 2 is double of T 1, we have: rms2rms1=2 v rms1 v rms2=2
Therefore, vrms2=2×rms1 v rms2=2× v rms1.
Given that vrms1=m/s v rms1=x m/s, we have: rms2=2×=2m/s v rms2=2× x =2 x m/s.
Hence, when the temperature is doubled and X2 molecules dissociate into atoms, the root mean square speed of the sample of gas becomes 2m/s2 x m/s.
The correct option is(C): 2x