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Question

Chemistry Question on States of matter

The RMS velocity of COCO gas molecules at 2727^{\circ}C is approximately 1000m/s1000\, m/s. For N2N_2 molecules at 600K600 \,K the RMS velocity is approximately

A

2000 m/s

B

1414 m/s

C

1000 m/s

D

1500 m/s

Answer

1414 m/s

Explanation

Solution

As from the formula, vrms=3RTMv_{ rms }=\sqrt{\frac{3 R T}{M}}
Given that (vrms)=1000m/s\left(v_{ rms }\right)_{\infty}=1000\, m / s
(Temp.)CO=27C=300K( Temp .)_{ CO }=27^{\circ} C =300 K
(Temp.) N2=600K_{ N _{2}}=600\, K
Now putting the values, we get
(vrms)CO(vrms)N2=3R3R×TCOMCO×MN2TN2\frac{\left(v_{ rms }\right)_{ CO }}{\left(v_{ rms }\right)_{ N _{2}}}=\sqrt{\frac{3 R}{3 R} \times \frac{T_{ CO }}{M_{ CO }} \times \frac{M_{ N _{2}}}{T_{ N _{2}}}}
1000(vms)N2=30028×28600\frac{1000}{\left(v_{m s}\right)_{N_{2}}}=\sqrt{\frac{300}{28} \times \frac{28}{600}}
=12=\frac{1}{\sqrt{2}}
or, (vms)N2=1000×1.414\left(v_{ ms }\right)_{ N _{2}}=1000 \times 1.414
=1414m/s=1414\, m / s