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Question

Question: The resistance of 1 N solution of acetic acid is 250 Ohm, when measured in a cell of cell constant \...

The resistance of 1 N solution of acetic acid is 250 Ohm, when measured in a cell of cell constant 1.15cm1.1.15cm^{- 1}. The equivalent conductance (in Ohm1cm2equiv1Ohm^{- 1}cm^{2}equiv^{- 1}) of 1 N acetic acid is.

A

4.6

B

9.2

C

18.4

D

0.023

Answer

4.6

Explanation

Solution

κ=G×cellconstant\kappa = G \times \text{cellconstant} =Cell constantR=1.15250= \frac{\text{Cell constant}}{R} = \frac{1.15}{250}

Λeq=κ×1000Normality=1.15250×10001\Lambda_{eq} = \frac{\kappa \times 1000}{\text{Normality}} = \frac{1.15}{250} \times \frac{1000}{1} =4.6Ω1cm2eq1.= 4.6\Omega^{- 1}cm^{2}eq^{- 1}.