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Question: The relative molecular masses of hydrogen, nitrogen, oxygen, and chlorine are double their relative ...

The relative molecular masses of hydrogen, nitrogen, oxygen, and chlorine are double their relative atomic masses.
(a)- True
(b)- False

Explanation

Solution

The atomic formula of hydrogen, nitrogen, oxygen, and chlorine are H, N, O, and ClH,\text{ }N,\text{ }O,\text{ and }Cl respectively, and the molecular formulas of hydrogen, nitrogen, oxygen, and chlorine are H2, N2, O2, and Cl2{{H}_{2}},\text{ }{{N}_{2}},\text{ }{{O}_{2}},\text{ and }C{{l}_{2}}.

Complete step by step answer:
Hydrogen is the element of s-block. Its atomic number is 1. The relative atomic mass of hydrogen is1.0079 g1.0079\text{ g}. The electronic configuration of hydrogen is 1s11{{s}^{1}}. So, one more electron is needed to complete its octet. So, in the molecular form, there are 2 hydrogen atoms.
The structure of molecular hydrogen is HHH-H. The molecular mass of hydrogen is2.016 g2.016\text{ g}. The molecular mass of hydrogen is double of the atomic mass of hydrogen.
Nitrogen is the element of p-block. Its atomic number is 7. The relative atomic mass of nitrogen is14.007 g14.007\text{ g}. The electronic configuration of nitrogen is 1s22s22p31{{s}^{2}}2{{s}^{2}}2{{p}^{3}}. So, it needs three more electrons to complete its octet. So, in the molecular form, there are 2 nitrogen atoms.
The structure of molecular nitrogen is: NNN\equiv N. The molecular mass of nitrogen is28.014 g\text{28}\text{.014 g}. The molecular mass of nitrogen is double of the atomic mass of nitrogen.
Oxygen is the element of p-block. Its atomic number is 8. The relative atomic mass of oxygen is15.999 g\text{15}\text{.999 g}. The electronic configuration of oxygen is 1s22s22p41{{s}^{2}}2{{s}^{2}}2{{p}^{4}}. So, two more electrons are needed to complete its octet. So, in the molecular form, there are 2 oxygen atoms.
The structure of molecular oxygen is O=OO=O. The molecular mass of oxygen is 31.998 g31.998\text{ g}. The molecular mass of oxygen is double of the atomic mass of oxygen.
Chlorine is the element of p-block. Its atomic number is 17. The relative atomic mass of chlorine is 35.453 g\text{35}\text{.453 g}. The electronic configuration of chlorine is 1s22s22p63s23p51{{s}^{2}}2{{s}^{2}}2{{p}^{6}}3{{s}^{2}}3{{p}^{5}}. So, it needs one more electron to complete its octet. So, in the molecular form, there are 2 chlorine atoms.
The structure of molecular chlorine is ClClCl-Cl. The molecular mass of chlorine is70.906 g\text{70}\text{.906 g}. The molecular mass of chlorine is double of the atomic mass of chlorine.
Hence, the statement “The relative molecular masses of hydrogen, nitrogen, oxygen, and chlorine are double their relative atomic masses” is true.

Note: As the number of atoms increases in its molecular formula, the molecular mass also increases with the number of atoms. For example, the atomic mass sulfur is 32 g32\text{ g} and in the molecular formula of sulfur has 8 sulfur atoms. The molecular mass of sulfur will be 8 x 32 = 256 g8\text{ x 32 = 256 g}.