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Question: The reduction potential of hydrogen electrode when placed in a buffer solution is found to be – 0.41...

The reduction potential of hydrogen electrode when placed in a buffer solution is found to be – 0.413V. The pH of the buffer is –

A

10

B

4

C

7

D

12

Answer

7

Explanation

Solution

- 0.413 = 0 - 0 .059 log1[H+] or = 0.4140.059- log H+ = pHor pH = 7\text{- 0.413 = 0 - 0 .059 log}\frac{1}{\left\lbrack H^{+} \right\rbrack}\text{ or = }\frac{\text{0.414}}{\text{0.059}}\text{- log }\text{H}^{+}\text{ = pHor } \text{pH = 7}