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Question

Chemistry Question on Bohr’s Model for Hydrogen Atom

The recoil speed of a hydrogen atom after it emits a photon in going from n=5n = 5, state to n=1n = 1 state is

A

4.718 ms1ms^{-1}

B

7.418 ms1ms^{-1}

C

4.178 ms1ms^{-1}

D

7.148 ms1ms^{-1}

Answer

4.178 ms1ms^{-1}

Explanation

Solution

E=Rhc(1125)E = R \, hc \left( 1 - \frac{1}{25} \right) Momentum of photon emitted is p=Ec=Rh(2425)p = \frac{E}{c} = R_{\infty} h \left( \frac{24}{25} \right) Recoil momentum of H atom will also be pp. mν=pm \nu = p ν=pm(1.097×107)(6.626×1034)24(25)(1.67×1027)\nu = \frac{p}{m} \frac{(1.097 \times 10^7)(6.626 \times 10^{-34})24}{(25)(1.67 \times 10^{-27})} \therefore ν=4.178ms1\nu = 4.178 \, ms^{-1}