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Question

Chemistry Question on Aldehydes, Ketones and Carboxylic Acids

The reagents which can be used to distinguish acetophenone from benzophenone is (are)

A

2,4-dinitrophenyl hydrazine

B

aqueous solution of NaHSO3NaHSO_3

C

Benedict reagent

D

l2l_2 and Na2CO3Na_2 CO_3

Answer

l2l_2 and Na2CO3Na_2 CO_3

Explanation

Solution

The structures of acetophenone and benzophenone are . When acetophenone containing is treated with l2l_2 and Na2CO3Na_2 CO_3 it forms yellow precipitate of CHI3CHI_3 whereas benzophenone does not give this test.Acetophenons gives iodoform test due to presence of'-COCH3 group.