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Question

Chemistry Question on Alkanes

The reagent which can do the conversion CH3COOHCH3CH2OHCH _{3} COOH \longrightarrow CH _{3}- CH _{2}- OH is

A

LiAIH4LiAIH_4 / ether

B

H2,PtH_2, Pt

C

NaBH4NaBH_4

D

NaNa and C2H5OHC_2H_5OH

Answer

LiAIH4LiAIH_4 / ether

Explanation

Solution

CH3COOHEthanoic acid LiAlH 4/ ether CH3CH2OHEthanol\underset{\text{Ethanoic acid}}{CH _{3} COOH} \xrightarrow{\text { LiAlH }_{4} / \text { ether }} \underset{\text{Ethanol}}{CH _{3} CH _{2} OH}

The reagent that can convert acetic acid (CH3COOH{CH_3COOH}) to ethanol (CH3CH2OH{CH_3CH_2OH}) is a reducing agent. One commonly used reducing agent for this conversion is lithium aluminum hydride (LiAlH4{LiAlH_4}) or sodium borohydride (NaBH4{NaBH_4}).

The reaction with lithium aluminum hydride (LiAlH4{LiAlH_4}) can be represented as follows:

CH3COOH+4LiAlH4CH3CH2OH+Al(OH)3+4LiH{CH_3COOH}+{4LiAlH_4}\rightarrow{CH_3CH_2OH}+{Al(OH)_3}+{4LiH}

This reaction reduces the carboxylic acid functional group (COOH{COOH}) of acetic acid to an alcohol functional group (CH3CH2OH{CH_3CH_2OH}) in ethanol.

It's important to note that this reaction is typically carried out under specific conditions, and caution should be exercised when working with reactive chemical reagents.