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Question

Chemistry Question on Equilibrium Constant

The reaction quotient (Q)( Q ) for the reaction: N2(g)+3H2(g)2NH3(g)N _{2}( g )+3 H _{2}( g ) \rightleftharpoons 2 NH _{3}( g ) is given by Q=[NH3]2[N2][H2]3.Q =\frac{\left[ NH _{3}\right]^{2}}{\left[ N _{2}\right]\left[ H _{2}\right]^{3}} . The reaction will proceed from right to left if :

A

Q=KCQ = K_C

B

Q<KCQ < K_C

C

Q>KCQ > K_C

D

Q=0Q = 0

Answer

Q>KCQ > K_C

Explanation

Solution

For reaction, N2(g)+3H2(g)2NH3(g){{N}_{2}}(g)+3{{H}_{2}}(g)\rightleftharpoons 2N{{H}_{3}}(g) QQ (Quotient) = [NH3]2[N2][H2]3,Δn=24=2\frac{{{[N{{H}_{3}}]}^{2}}}{[{{N}_{2}}]\,{{[{{H}_{2}}]}^{3}}},\Delta n=2-4=-2 At equilibrium QQ is equal to KC{{K}_{C}} but for the progress of reaction towards right side Q>KCQ>{{K}_{C}} where KC{{K}_{C}} is the equilibrium constant.