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Question

Chemistry Question on Balancing a redox reaction

The reaction P4+3NaOH+3H2O3NaH2PO2+PH3{ P_4 + 3NaOH + 3H_2O \to 3NaH_2PO_2 + PH_3} is an example of

A

disproportionation reaction

B

neutralization reaction

C

double decomposition reaction

D

pyrolytic reaction

Answer

disproportionation reaction

Explanation

Solution

Given reaction,
P4+3NaOH+3H2O>3NaH2PO2+PH3{P4 +3NaOH + 3H2O -> 3\,NaH2PO2 +PH3}
Oxidation state of PP in P4=0P_4 = 0
Oxidation state of PP in PH3=3PH_3 = -3
Oxidation state of PP in
NaH2PO2=+1{NaH_2PO_2 = + 1}
so, P40>PH33+H2PO2+1 {P^0_4 -> \overset{-3}{PH_3} +H2\overset{+1}{PO^{-}_2}}
Hence, this reaction is an example of disproportionation reaction. It is a chemical reaction, typically a redox reaction, where a molecule is transformed into two or more dissimilar products.