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Question

Chemistry Question on p -Block Elements

The reaction of HClO3 with HCl gives a paramagnetic gas, which upon reaction with O3 produces

A

Cl2OCl _2 O

B

ClO2ClO _2

C

Cl2O6Cl _2 O _6

D

Cl2O7Cl _2 O _7

Answer

Cl2O6Cl _2 O _6

Explanation

Solution

The correct option is C Cl2O6\text{Cl}_2\text{O}_6
2HClO3+2HCl2ClO2+Cl2+2H2O2HClO_3+2HCl→2ClO_2+Cl_2+2H_2O

ClO2\text{ClO}_2 produced here is a paramagnetic gas.

2ClO2+2O3Cl2O6+2O22\text{ClO}_2 + 2\text{O}_3 \rightarrow \text{Cl}_2\text{O}_6 + 2\text{O}_2