Question
Chemistry Question on Thermodynamics terms
The reaction of cyanamide, NH2CN(s), with dioxygen was carried out in a bomb calorimeter, and ∆U was found to be –742.7 kJ mol–1 at 298 K. Calculate enthalpy change for the reaction at 298 K.
NH2CN(g)+23O2(g)→N2(g)+CO2(g)+H2O(l)
Answer
Enthalpy change for a reaction (∆H) is given by the expression,
∆H=∆U+∆ngRT
Where,
∆U = change in internal energy
∆ng = change in number of moles
For the given reaction,
∆ng = ∑ng (products) – ∑ng (reactants)
∆ng = (2–2.5) moles
∆ng = –0.5 moles
And, ∆U=–742.7 kJmol–1
T=298 K
R=8.314×10–3 kJmol–1K–1
Substituting the values in the expression of ∆H:
∆H=(–742.7 kJmol–1)+(–0.5 mol)(298 K)(8.314×10–3kJ mol–1K–1)
∆H=–742.7–1.2
∆H=–743.9 kJ mol–1