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Question

Question: The ratio of acid strength of HOCN and HCN is about Given K<sub>a</sub> of HOCN = 1.2 × 10<sup>–4</...

The ratio of acid strength of HOCN and HCN is about

Given Ka of HOCN = 1.2 × 10–4 and Ka of HCN = 4.2 × 10–10

A

548 : 1

B

1 : 548

C

2.86 × 105 : 1

D

2.86 × 104 : 1

Answer

548 : 1

Explanation

Solution

[H+]HOCN[H+]HCN\frac { \left[ \mathrm { H } ^ { + } \right] _ { \mathrm { HOCN } } } { \left[ \mathrm { H } ^ { + } \right] _ { \mathrm { HCN } } } =

= (1.2×1044.2×1010)1/2\left( \frac { 1.2 \times 10 ^ { - 4 } } { 4.2 \times 10 ^ { - 10 } } \right) ^ { 1 / 2 } = 535