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Question

Chemistry Question on Surface Chemistry

The rate of reactions exhibiting negative activation energy

A

decreases with increasing temperature

B

increases with increasing temperature

C

does not depend on temperature

D

depends on the height of the potential barrier

Answer

decreases with increasing temperature

Explanation

Solution

The rate of reactions exhibiting negative activation energy decreases with increasing temperature because the reaction with the greater activation energy will be faster at the higher temperature and k=AeEa/RTk=A e^{-E_{a} / R T} when Ea=veE_{a}=-v e