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Question

Chemistry Question on Chemical Reactions

The rate of a reaction quadruples when temperature changes from 27°c to 57°c. Calculate the energy of activation
Given R=8.314 J K-1 mol-1, log 4=0.6021

A

38.04 KJ/mol

B

380.4 KJ/mol

C

3.80 KJ/mol

D

3804 KJ/mol

Answer

38.04 KJ/mol

Explanation

Solution

Step 1: Use Arrhenius equation:

ln(k2k1)=EaR(T2T1T1T2)\ln\left(\frac{k_2}{k_1}\right) = \frac{E_a}{R}\left(\frac{T_2 - T_1}{T_1T_2}\right)

Step 2: Plug values:

ln4=Ea8.314×30300×330\ln 4 = \frac{E_a}{8.314} \times \frac{30}{300 \times 330}

Ea=38.04kJ/molE_a = 38.04 \, kJ/mol