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Question

Chemistry Question on Chemical Kinetics

The rate equation for a reaction : ABA \rightarrow B is r=K[A]r = K[A]^\circ. If the initial concentration of the reactant is a mol dm3dm^{-3}, the half life period of the reaction is

A

aK\frac {a} {K}

B

2aK\frac {2a} {K}

C

a2K\frac {a} {2K}

D

Ka\frac {K} {a}

Answer

a2K\frac {a} {2K}

Explanation

Solution

ABA \longrightarrow B r=k[A]0\because\,\,\,\,\,r=k[A]^{0} or r=k\,\,\,\,\,\,r=k This is a zero order reaction. t1/2=a2k\therefore \,\,\,\,\,t_{1 / 2}=\frac{a}{2 k}