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Question

Chemistry Question on Chemical Kinetics

The rate constant for a first order reaction is given by the following equation :
ln k=33.242.0×104 KTln\ k=33.24−\frac {2.0×10^4\ K}{T}
The activation energy for the reaction is given by ______ kJmol1kJ mol^{–1}. (In nearest integer)
(Given : R=8.3JK1mol1R = 8.3 JK^{–1} mol^{–1})

Answer

Given that,
ln k=33.242.0×104 KTln\ k=33.24−\frac {2.0×10^4\ K}{T}
So, EaR=2×104\frac {E_a}{R} = 2 \times 10^4
The activation energy for the reaction,
Ea=2×104×8.3E_a = 2 × 10^4 × 8.3
Ea=166×103 J/molE_a = 166 × 10^3\ J/mol
Ea=166 kJ/molE_a= 166\ kJ/mol

So, the answer is 166 kJ/mol166\ kJ/mol.