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Question

Chemistry Question on The solid state

The radius of the largest sphere which fits properly at the centre of the edge of body centred cubic unit cell is : (Edge length is represented by 'a') :

A

0.134 a

B

0.027 a

C

0.067 a

D

0.047 a

Answer

0.067 a

Explanation

Solution


a=2(R+r)a = 2\left(R + r\right)
a2=(R+r)\frac{a}{2} =\left(R+r\right) .....(1)

a3=4Ra\sqrt{3} =4R .....(2)

Using (1) & (2)

a2=a34=r \frac{a}{2} = \frac{a\sqrt{3}}{4} =r
a(234)=ra\left(\frac{2-\sqrt{3}}{4}\right)=r
r=0.067ar=0.067\, a