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Question

Chemistry Question on coordination compounds

The radius of a calcium ion is 94 pm and of the oxide ion is 146 pm. The possible crystal structure of calcium oxide will be

A

tetrahedral

B

trigonal

C

octahedral

D

pyramidal

Answer

octahedral

Explanation

Solution

As per formula, radius ratio
=radiusofcationradiusofanionm= \frac{radius\, of \,cation}{radius \,of \,anion}m
=94146=0.643=\frac{94}{146}=0.643
Since the value is between 0.414 - 0.732 hence the coordination no. will be 6 and geometry will be octahedral.
So, the correct option is (C): octahedral.