Question
Chemistry Question on Chemical Kinetics
The radioactivity of a sample is R1 at a time T1 and R2 at times T2 . the half-life of the specimen is T, the number of atoms that have disintegrated at the time (T2−T1) is proportional to
A
R1T1−R2T2
B
R1−R2
C
TR1−R2
D
(R1−R2)T
Answer
(R1−R2)T
Explanation
Solution
R1=N1λ and R2=N2λ Also T=λloge2 Or λ=Tloge2 ∴R1−R2=(N1−N2)λ =(N1−N2)Tloge2 ∴(N1−N2)=loge2(R1−R2)T ie, (N1−N2)∝(R1−R2)T