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Question

Chemistry Question on Bohr’s Model for Hydrogen Atom

The radiation corresponding to 323\rightarrow2 transition of hydrogen atom falls on a metal surface to produce photoelectrons. These electrons are made to enter a magnetic field of 3×1043\times10^{-4}T. If the radius of the largest circular path followed by these electrons is 10.0 mm, the work function of the metal is close to

A

1.8 eV

B

1.1 eV

C

0.8 eV

D

1.6 eV

Answer

1.1 eV

Explanation

Solution

Thinking Process The problem is based on frequency dependence of photoelectric emission. When incident light with certain frequency (greater than on the threshold frequency is focus on a metal surface) then some electrons are emitted from the metal with substantial initial speed. When an electron moves in a circular path, then r=mveBr2e2B22=m2v22r=\frac{mv}{eB} \Rightarrow \frac{r^2e^2B^2}{2}=\frac{m^2v^2}{2} KEmax=(mv)22mr2e2B22m=(KE)maxKE_{max}=\frac{(mv)^2}{2m}\Rightarrow \frac{r^2e^2B^2}{2m}=(KE)_{max} Work function of the metal (W), i.e. W=hvKEmaxW= hv-KE_{max} 1.89=r2e2B22m12eV=r2eB22meV1.89-\oint=\frac{r^2e^2B^2}{2m}\frac{1}{2}eV=\frac{r^2eB^2}{2m}eV [hv1.89eV,hv \rightarrow 1.89 eV, for the transition on from third to second orbit of H-atom] =100×106×1.6×1019×9×1082×9.1×1031=\frac{100\times10^{-6}\times1.6\times10^{-19}\times9\times10^{-8}}{2\times9.1\times10^{-31}} =1.891.6×92×9.1\oint=1.89-\frac{1.6\times9}{2\times9.1} =1.890.79=1.1eV=1.89-0.79=1.1 eV