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Question

Chemistry Question on Equilibrium

The pHpH of solution containing 0.10M0.10\, M sodium acetate and 0.03M0.03\, M acetic acid is (pKa for CH3COOH=4.57)\left( pK _{a} \text { for } CH _{3} COOH =4.57\right)

A

4.09

B

6.09

C

5.09

D

7.09

Answer

5.09

Explanation

Solution

According to Henderson's equation, pH=pKa+log[ salt ][ acid ]p H=p_{K a}+\log \frac{[\text { salt }]}{[\text { acid }]} CH3COOH+NaOHCH3COONa+H2OCH _{3} COOH + NaOH \rightarrow CH _{3} COONa + H _{2} O Putting the values, we get: pH=4.57+log0.100.03p H=4.57+\log \frac{0.10}{0.03} pH=5.09\Rightarrow p H=5.09